WHMIS
MATERIAL SAFETY DATA SHEET
PRODUCT INFORMATION
VALCOOL® VNT® 940C CARBIDE GRINDING FLUID CONCENTRATE |
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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Valenite Modco Ltd. 4510 Rhodes Drive Unit 920 Windsor, Ontario Canada N8W5K5 |
Emergency Telephone Number: 1-800-424-9300 (CHEMTREC) Information Telephone Number: 1-800-488-9073 Generic Name: Water Soluble Metalworking Fluid Concentrate Product Name(s) & Code(s): VNT 940C UNDYED 418; |
EMERGENCY INFORMATION |
Product is alkaline. Product is a primary eye irritant. Highway spills could result in slippery conditions. No other significant health effects are associated with this material. |
HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
HAZARDOUS INGREDIENTS/IDENTITY INFORMATION |
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These ingredients may contribute to the acute product hazards listed under the Potential Health Effects section. Other substances, not Hazardous under the OSHA Hazard Communication Standard may be present. Further composition information may be available to health professionals as provided in the Standard. | |||
HAZARDOUS COMPONENTS |
CAS # |
% RANGE |
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Triethanolamine |
102-71-6 |
10-30 |
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Pelargonic acid |
112-05-0 |
1-5 |
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Neodecanoic acid |
26896-20-8 |
1-5 |
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Aminomethylpropanol |
124-68-5 |
5-10 |
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Benzotriazole |
95-14-7 |
5-10 |
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TOXICOLOGICAL PROPERTIES
POTENTIAL HEALTH EFFECTS OF DIRECT EXPOSURE |
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Product Concentrate |
Product at Use Dilution | |||
Inhalation |
Not Applicable. |
Extended Exposure to mists may cause upper respiratory irritation. |
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Eye Contact |
Product is a primary eye irritant. |
Will cause stinging sensation in the eye. |
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Skin Contact |
Product is not a primary skin irritant. |
Not irritating to the skin when used as directed and good personal hygiene is practiced. |
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Ingestion |
Not orally toxic. |
Swallowing small quantities may cause nausea or diarrhea. |
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When used in applications generating high levels of mist, operator exposure can be minimized by proper ventilation, use of mist collectors or splash guards, as appropriate. If there is doubt about actual mist levels present, monitoring should be conducted. Mild skin irritation (redness and dryness of hands) may be experienced when the diluted product has been contaminated by certain oils, by dissolved metals, or when mix ratio is too strong. When problems occur, use of water-resistant barrier creams may be a temporary control measure. Contact Canadian VALCOOL® Technical Services for specific recommendations (1-800-488-9073). Repeated excessive exposures to high amounts of triethanolamine may cause liver and kidney effects. |
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Carcinogen Listings |
NTP: No |
IARC: No |
OSHA: No |
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Signs and symptoms of exposure: Eye injury may result from contact with concentrated product. Skin irritation can result from improper use and handling of concentrate or mix. |
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Medical conditions generally aggravated by exposure: May aggravate existing skin irritation where further defatting or skin penetration could occur. |
CONC. (%) |
ACUTE ORAL TOXICITY (g/kg) (LD50-Rats) |
ACUTE INHALATION TOXICITY (mg/l) (Rats) |
ACUTE EYE IRRITATION (Rabbits) |
PRIMARY SKIN IRRITATION (Rabbits) |
CORROSIVITY (Rabbits) |
ACUTE DERMAL TOXICITY (g/kg) (LD50-Rabbits) |
100 20 |
Above 5 |
Above 20 |
Positive Negative |
Negative |
Negative |
Above2 |
EXPOSURE GUIDELINES |
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REGULATED MATERIAL |
NIOSH REL |
OSHA PEL |
OSHA STEL |
ACGIH TLV |
ACGIH STEL | |||
Metalworking Fluid Mist |
0.5 mg/M3 |
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Triethanolamine |
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5 mg/M3 |
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SECOND PRIORITY SUBSTANCES LIST |
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Material |
205 Liter Drums to Reach 1000 Kilogram Trigger |
Not Applicable |
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All ingredients of this product are on the Canadian NDSL or DSL. |
HAZARD CATEGORIES: Acute Health: Yes Chronic Health: No Fire: No Sudden Release of Pressure: No Reactive: No |
WHMIS Classification: D2B, |
EMERGENCY AND FIRST AID PROCEDURES
Eyes: In case of eye contact with concentrated product or diluted mix, flush immediately with running water for 15 minutes, then promptly get medical attention to check for possible irritation. |
Skin contact: In case of skin contact with product concentrate, wash with water as soon as possible. Diluted product is not irritating to the skin when used as recommended and good personal hygiene is practiced. Remove severely contaminated clothing, including shoes. Launder before reuse. If irritation persists, get medical attention. |
Ingestion: If concentrate or mix is swallowed, do not induce vomiting. Dilute by drinking water or milk. Immediately contact physician and obtain treatment. Swallowing small quantities of diluted product is not expected to cause injury or illness; but, as should be expected when drinking oily, soapy water, nausea, diarrhea or abdominal distress may be experienced. |
Inhalation: Not expected to be a probable route of exposure to product concentrate. Inhalation of diluted mix can occur in applications where high mist levels are generated. OSHA has set a PEL of 15 mg/M3 for any airborne particulate as a nuisance level of exposure. NIOSH has set a REL of 0.5 mg/M3 for metalworking fluid mist. |
PREVENTIVE MEASURES
Respiratory Protection: Product concentrate is not volatile. No misting would be expected when handling product concentrate. In applications where time-weighted exposures are 0.5 to 5 mg/M3, mist reduction through improved ventilation, mist collection or process modification is recommended by NIOSH. Where this is not possible, NIOSH recommends the use of any air purifying, half-mask respirator including a disposable respirator, equipped with any P- or R-series particulate filter. If the average exposure will exceed 5 mg/M3, NIOSH recommends use of a powered, air-purifying respirator equipped with a hood or helmet and a HEPA filter. If respiratory problems are present when mist levels are < 0.5 mg/M3, respiratory protection should be based on the individual recommendation of a qualified health care provider. Caution: The appropriate use and type of respirator is dependent upon use of the product and local operating conditions. |
Ventilation: For most applications, normal shop ventilation is adequate. However, when high mist levels are generated or where machines are close together or ventilation is inadequate, operators may experience respiratory irritation. For such applications, use of splash guards or mist collectors is recommended. |
Eye Protection: Safety shield or goggles required when handling concentrated product. |
Other protective clothing or equipment: Effective metalworking plant protective clothing as appropriate. |
Work/Hygiene Practices: Good personal hygiene should always be followed. |
Protective Gloves: Impervious gloves, such as nitrile gloves, are recommended when handling product concentrate. |
ACCIDENTAL RELEASE MEASURES |
Contain the spill, collect on absorbent material and discard as dictated by Federal, provincial and local regulations that may apply. Flush area thoroughly with water. |
Reportable Quantity: None |
WASTE DISPOSAL |
For Used Mix: Disposal procedures must comply with local, county, state and Federal regulations. If pre-treatment is needed, ultrafiltration or evaporation may be used. Contact VALCOOL Technical Services at 1-800-488-9073 for assistance. |
For Unused Concentrate: Concentrate is not a hazardous waste, as defined under 40 CFR 261. |
"Empty" Containers will contain a residue which is not considered a hazardous waste under RCRA regulations. Drums can be drained to a "drip dry" condition by inversion and can be offered for recycling or scrap. |
HANDLING AND STORAGE |
Use only as recommended by Valenite. Avoid all contact of concentrate with eyes or skin. Do not swallow. If frozen, product separates. Thaw completely at room temperature and stir thoroughly prior to use. |
Other Precautions - Contains amines. Do not add sodium nitrite or other nitrosating agents to this product; suspected cancer-causing nitrosamines could be formed. |
TRANSPORT INFORMATION |
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Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101): |
Hazard Class (49 CFR 172.101): |
BY LAND |
Not a hazardous material. |
Not Applicable |
BY AIR OR VESSEL (49 CFR 175-176) |
Not a hazardous material. |
Not Applicable |
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U.S. Harmonized Tariff Code: 3403.99.0000 |
FIRE AND EXPLOSION HAZARD DATA
Flash Point (COC): Not Applicable |
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Flammable Limits: Lower Explosive Limit: Not determined |
Upper Explosive Limit: Not determined | ||||
Extinguishing Media: Not Applicable |
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Special Firefighting Procedure: None |
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Unusual Fire and Explosion Hazards: None |
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Hazardous Combustion Products: Smoke, fumes, oxides of carbon |
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NFPA/HMIS Codes: |
Health 1 |
Flammability 0 |
Reactivity 0 |
Other - |
PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point |
100oC |
Evaporation Rate |
Like water when diluted |
Specific Gravity |
1.08 |
Solubility in Water |
100% Miscible |
Vapor Pressure (mm Hg) |
Not Determined |
Appearance/Odor |
Clear, slight chemical |
Melting Point |
Not Determined |
pH (concentrate) |
10.3 |
Vapor Density |
Not Determined |
pH (5.0% mix) |
9.1 |
Physical State: Liquid |
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Volatile Organic Content (concentrate - by ASTM Method 2369 (Standard Test Method for Volatile Content of Coatings)): 4.36% |
REACTIVITY
Stability: Stable |
Conditions to Avoid: Not Applicable |
Materials to Avoid: Avoid contact with strong acids or oxidizers to product concentrate. |
Hazardous Polymerization: Will not occur. |
Combustion Products: Smoke, fumes, oxides of carbon |
PREPARATION INFORMATION
MSDS: VNT940C |
FS 9096: 1514 |
DATE CREATED: 06/02/2002 |
Prepared by Milacron Cutting Process Technology Regulatory Affairs Group 513-458-8182 |
GLOSSARY OF ABBREVIATIONS |
ACGIH |
American Conference of Governmental Industrial Hygienists |
CAS |
Chemical Abstracts Service |
CERCLA |
Comprehensive Environmental Response Compensation and Liability Act |
CFR |
Code of Federal Regulations |
COC |
Cleveland Open Cup |
DOT |
Department of Transportation |
EPCRA |
Emergency Planning and Community Right-to Know Act (aka SARA) |
IARC |
International Agency for Research on Cancer |
NA |
Not Applicable |
ND |
Not Determined |
NIOSH |
National Institute for Occupational Safety and Health |
NTP |
National Toxicology Program |
OSHA |
Occupational Safety and Health Administration |
PEL |
Permissible Exposure Limit |
RCRA |
Resource Conservation and Recovery Act |
REL |
Recommended Exposure Limit |
SARA |
Superfund Amendments and Reauthorization Act |
STEL |
Short-Term Exposure Limit |
TCLP |
Toxicity Characteristics Leaching Procedure |
TLV |
Threshold Limit Value |
TSCA |
Toxic Chemicals Control Act |
VOC |
Volatile Organic Compounds |
NOTE: The opinions expressed herein are those of qualified experts within Valenite Incorporated and of their suppliers. We believe that the information contained herein is current as of the date of this Material Data Sheet. Since the use of this information and of these opinions and the condition and use of the product are not within the control of Valenite Incorporated, it is the user's obligation to determine the conditions of safe use of the product. This is the last page |