SAFETY DATA SHEET Ref. No.

66080

1. PRODUCT AND COMPANY IDENTIFICATION

 

Trade Name

ROCOL SPATTER RELEASE SPRAY

Manufacturer/Supplier

ROCOL Lubricants

Address

ROCOL House,

Swillington, Leeds,

LS26 8BS,

ENGLAND

Phone Number

+44 (0) 113 2322700

Fax Number

+44 (0) 113 2322760

Emergency Phone Number

+44 (0) 113 2322600

2. COMPOSITION/INFORMATION ON THE COMPONENTS

Hazardous Components in Product for EC

Component Name

Codes

Concentration

R Phrases

Classification

DICHLOROMETHANE

75-09-2

60.00 - 80.00

R40

CC3

CARBON DIOXIDE AEROSOL PROPELLANT

000124-38-9

1.00 - 5.00

   

SOLVENT REFINED MINERAL OIL

064741-95-3

10.00 - 30.00

   

R40

R40 Possible risk of irreversible effects.

CC3

Carcinogen, Category 3



3. HAZARD IDENTIFICATION

 

Main Hazards

Harmful by inhalation. Possible risk of irreversible effects.

Health Effects - Eyes

Liquid may cause slight transient irritation.

Health Effects - Skin

Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis.

Health Effects - Ingestion

Swallowing may have the following effects:- dizziness. light headedness. drowsiness. nausea.

Health Effects - Inhalation

Exposure to vapour at high concentrations may have the following effects:- dizziness. light headedness. drowsiness. headache.

4. FIRST AID MEASURES

 

First Aid - Eyes

Wash out eye with plenty of water. Obtain medical attention if soreness or redness persists.

First Aid - Skin

Wash skin with soap and water. Apply a reconditioning skin cream.

First Aid - Ingestion

Do not induce vomiting. Obtain medical attention.

First Aid - Inhalation

Remove from exposure. Keep warm and at rest. Seek medical attention if you feel unwell.

5. FIRE FIGHTING MEASURES

 

Extinguishing Media

Use foam, dry chemical or carbon dioxide. Keep containers and surroundings cool with water spray.

Unsuitable Extinguishing Media

Do not use water jet.

Special Hazards of Product

Containers may explode in heat of fire. This product may give rise to hazardous fumes in a fire.

Protective Equipment for Fire-Fighting

Wear self contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

 

Personal Precautions

Ventilate the area. Wear appropriate protective clothing. Material can create slippery conditions underfoot.

Environmental Precautions

Try to prevent the material from entering drains or water courses.

Spillages

Allow to evaporate if it is safe to do so or contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal.

7. HANDLING AND STORAGE

 

Handling

Use in well ventilated area. Guard against the possibility of weld spatter piercing the container.

Storage

Storage area should be: out of direct sunlight. Storage temperature should be kept below 50 °C.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Standards

DICHLOROMETHANE

UK EH40: MEL 100ppm 8h TWA. UK EH40: MEL 300ppm 15min TWA.

CARBON DIOXIDE AEROSOL PROPELLANT

UK EH40: OES 5000ppm (9000mg/m3) 8h TWA. UK EH40: OES 15000ppm (27000mg/m3) 15min TWA.

OIL MIST, MINERAL

UK EH40: OES 5mg/m3 8h TWA. UK EH40: OES 10mg/m3 15min TWA.

Engineering Control Measures

Exposure to this material may be controlled in a number of ways. The measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. Use of the basic principles of Industrial Hygiene will enable this material to be used safely.

Respiratory Protection

Respiratory protection if there is a risk of exposure to high vapour concentrations.

Hand Protection

Use a good quality barrier cream.

Eye Protection

Chemical goggles if there is a risk of eye contact.

Body Protection

Normal work wear.

Protection During Application

During application, adequate ventilation must be provided.

9. PHYSICAL AND CHEMICAL PROPERTIES

 

Physical State

Liquid.

Colour

Amber.

Odour

Characteristic.

Boiling Range/Point (°C)

40 (based on major component)

Flash Point (PMCC) (°C)

Exceeds 150.

Explosion Limits (%)

14.8 to 22.0. (based on major component)

Solubility in Water (kg/m3)

Insoluble.

Vapour Pressure (mm.Hg./20 °C)

340

Density (kg/m3)

>1. (measured as kg/litre)

Auto-flammability (ºC)

Above 150.

Viscosity (cSt)

Mobile liquid at ambient temperatures.

Vapour Density (Air = 1)

Heavier than air.

Evaporation Rate

2 (referenced as n-butyl acetate = 1)

10. STABILITY AND REACTIVITY

 

Stability

Stable under normal conditions.

Conditions to Avoid

Exposure to direct sunlight. Temperatures in excess of 50 °C.

Materials to Avoid

Strong oxidising agents. Metals such as sodium, potassium and barium. Fine powders of light metals and their alloys such as Al, Mg, Zn. Ti, etc.

Hazardous Decomposition Products

Contact with naked flames or red hot surfaces may produce: hydrogen chloride. phosgene. Combustion may also generate: smoke, possibly thick and choking, resulting in zero visibility.

11. TOXICOLOGICAL INFORMATION

 

Acute Toxicity

Harmful by inhalation.

Chronic Toxicity/Carcinogenicity

A component of this product is classified by EEC as a category 3 carcinogen:- substances which cause concern owing to possible carcinogenic effects but in respect of which the information is not adequate for a satisfactory assessment.

In view of the postulated mechanism and the high dose levels required to induce tumours experimentally, exposures to this product within recommended standards are not considered to represent a carcinogenic risk to man.

12. ECOLOGICAL INFORMATION

 

Mobility

The product will leach into soil. If released to water the product will sink.

Persistence/Degradability

The product is expected to be resistant to biodegradation.

Bio-accumulation

Product is not expected to bioaccumulate.

13. DISPOSAL

 

Product Disposal

Dispose of in accordance with all applicable local and national regulations.

Container Disposal

Plastic caps and empty aerosols may be recycled via appropriate routes. Empty aerosols may be disposed of by authorised landfill. Do not incinerate closed containers.

14. TRANSPORT INFORMATION

 

UN Number

1950

UN Proper Shipping Name

Aerosols

UN Class

2

UN Subsidiary Risk

6.1

UK Proper Shipping Name

Aerosols

UK Classification

2.2

UK Subsidiary Risk

6.1

UK Transport Category

2

ADR/RID - Description

Aerosols.

ADR/RID - Class

2

ADR/RID - Item No.

5T

IMDG - Proper Shipping Name

Aerosols

IMDG - Class

2.2

IMDG - Subsidiary Risk

6.1

IMDG - Marine Pollutant

No

IMDG - Ems Number

2-13

IATA - Proper Shipping Name

Aerosols, non-flammable, n.o.s, containing substances in Division 6.1, Packing Group III.

IATA - Class

2.2

IATA - Subsidiary Risks

6.1

Tremcard No. TEC(R)

20G26

15. REGULATORY INFORMATION

Labelling Information

Harmful

 

 

 

R phrases

R20 Harmful by inhalation. R40 Possible risk of irreversible effects.

S phrases

S23 Do not breathe spray. S38 In case of insufficient ventilation, wear suitable respiratory equipment.

S24 Avoid contact with skin.

S2 Keep out of reach of children.

Contains

Dichloromethane

16. OTHER INFORMATION

 

Product Use

For industrial use only. Prevention of weld spatter adhesion.

MSDS first issued

31 July 1997

MSDS data revised

21 May 2001

17. NATIONAL LEGISLATION

 

EC Legislation

EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations.

EC Directive 88/379/EEC relating to the classification, packaging and labelling of dangerous preparations.

EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers.

UK Guidance Publications

EH40, Occupational Exposure Limits, HSE. Revised Annually.

Approved Supply List (Third Edition)(ISBN 0-7176-1116-7) Introduction, page xiv et seq - Notes H & L apply to the complex oil derived constituents of this preparation.

To the best of our knowledge, the information contained herein is accurate. Although certain hazards may be described we cannot predict that these are the only hazards, or combination of hazards, that may exist in a workplace. This Safety Data Sheet, therefore, forms a component only of a risk assessment carried out by, or on behalf of, the user.