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SAFETY DATA SHEET Ref. No. |
57015 |
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1. PRODUCT AND COMPANY IDENTIFICATION | ||
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Trade Name |
ROCOL LAYOUT INK SPRAY - WHITE & BLUE | |
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Manufacturer/Supplier |
ROCOL Lubricants | |
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Address |
ROCOL House, Swillington, Leeds, LS26 8BS, ENGLAND | |
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Phone Number |
+44 (0) 113 2322700 | |
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Fax Number |
+44 (0) 113 2322760 | |
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Emergency Phone Number |
+44 (0) 113 2322600 | |
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2. COMPOSITION/INFORMATION ON THE COMPONENTS |
Hazardous Components in Product for EC
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Component Name |
Codes |
Concentration |
R Phrases |
Classification | ||
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HYDROCARBON AEROSOL PROPELLANT (<0.1% 1,3 BUTADIENE) |
68476-85-7 |
30.00 - 40.00 |
R12 |
F+ | ||
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TOLUENE |
000108-88-3 |
1.00 - 5.00 |
R11, R20 |
Xn, F | ||
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ACETONE |
000067-64-1 |
30.00 - 60.00 |
R11, R36, R66, R67 |
F, Xi | ||
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XYLENE, MIXTURE OF ISOMERS |
001330-20-7 |
5.00 - 15.00 |
R10, R20/21, R38 |
Xn, Xi, f | ||
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R10 |
R10 Flammable. | |||||
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R11 |
R11 Highly flammable. | |||||
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R12 |
R12 Extremely flammable. | |||||
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R20 |
R20 Harmful by inhalation. | |||||
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R20/21 |
R20/21 Harmful by inhalation and in contact with skin. | |||||
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R36 |
R36 Irritating to eyes. | |||||
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R38 |
R38 Irritating to skin. | |||||
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R66 |
R66 Repeated exposure may cause skin dryness or cracking. | |||||
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R67 |
R67 Vapours may cause drowsiness and dizziness. | |||||
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F |
F - Highly flammable | |||||
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F+ |
F+ - Extremely flammable | |||||
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Xi |
Xi - Irritant | |||||
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Xn |
Xn - Harmful | |||||
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f |
Flammable | |||||
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3. HAZARD IDENTIFICATION | ||
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Main Hazards |
Extremely flammable. Irritating to eyes. | |
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Health Effects - Eyes |
Liquid will cause conjunctival irritation. | |
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Health Effects - Skin |
Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. | |
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Health Effects - Ingestion |
Swallowing may have the following effects:- nausea. drowsiness. | |
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Health Effects - Inhalation |
Exposure to vapour at high concentrations may have the following effects:- drowsiness. | |
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4. FIRST AID MEASURES | ||
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First Aid - Eyes |
Wash out eye with plenty of water. Obtain medical attention if soreness or redness persists. | |
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First Aid - Skin |
Wash skin with soap and water. Apply a reconditioning skin cream. | |
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First Aid - Ingestion |
Do not induce vomiting. Obtain medical attention. | |
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First Aid - Inhalation |
Remove from exposure. | |
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5. FIRE FIGHTING MEASURES | ||
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Extinguishing Media |
Keep containers and surroundings cool with water spray. Use foam, dry chemical or carbon dioxide. | |
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Unsuitable Extinguishing Media |
Do not use water jet. | |
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Special Hazards of Product |
Containers may explode in heat of fire. This product may give rise to hazardous fumes in a fire. | |
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Protective Equipment for Fire-Fighting |
Wear self contained breathing apparatus. | |
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6. ACCIDENTAL RELEASE MEASURES | ||
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Personal Precautions |
Eliminate all sources of ignition. Ventilate the area. | |
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Environmental Precautions |
Try to prevent the material from entering drains or water courses. Advise Authorities if spillage has entered water course or sewer or has contaminated soil or vegetation. | |
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Spillages |
Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. | |
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7. HANDLING AND STORAGE | ||
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Handling |
Use in well ventilated area. | |
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Storage |
Storage temperature should be kept below 50 °C. Storage area should be: out of direct sunlight. | |
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION | ||
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Occupational Exposure Standards | ||
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HYDROCARBON AEROSOL PROPELLANT (<0.1% 1,3 BUTADIENE) |
Occupational exposure standards for significant components are: UK EH40: OES 1750mg/m3 8h TWA. UK EH40: OES 2180mg/m3 15min TWA. (LPG) UK EH40: OES 1450mg/m3 8h TWA. UK EH40: OES 1810mg/m3 15min TWA. (Butane) The minimal atmospheric oxygen concentration should be 18% by volume under normal atmospheric pressure. | |
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TOLUENE |
UK EH40: OES 50ppm (191mg/m3) 8h TWA. UK EH40: OES 150ppm (547mg/m3) 15min TWA. | |
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ACETONE |
UK EH40: OES 750ppm 8h TWA. UK EH40: OES 1500ppm 15min TWA. | |
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XYLENE, MIXTURE OF ISOMERS |
UK EH40: OES 100ppm (441mg/m3) 8h TWA. UK EH40: OES 150ppm (662mg/m3) 15min TWA. Can be absorbed through skin. FRG: MAK 100ppm (440mg/m3) 8h TWA. Peak limitation category II,1 MAK Pregnancy group 0. ACGIH: TLV 100ppm (434mg/m3) 8h TWA. ACGIH: STEL 150ppm (651mg/m3) 15min TWA. A4 - not classifiable as a human carcinogen. | |
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Engineering Control Measures |
Exposure to this material may be controlled in a number of ways. The measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. Use of the basic principles of Industrial Hygiene will enable this material to be used safely. | |
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Respiratory Protection |
Respiratory protection if there is a risk of exposure to high vapour concentrations. | |
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Hand Protection |
Use a good quality barrier cream. | |
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Eye Protection |
Chemical goggles if there is a risk of eye contact. | |
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Body Protection |
Normal work wear. | |
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Protection During Application |
During application, adequate ventilation must be provided. | |
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9. PHYSICAL AND CHEMICAL PROPERTIES | ||
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Physical State |
Liquid. | |
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Colour |
Varies with product. | |
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Odour |
Characteristic. | |
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Boiling Range/Point (°C) |
Boils above 50. | |
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Flash Point (PMCC) (°C) |
<0 (based on major component) | |
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Explosion Limits (%) |
Not determined. | |
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Solubility in Water (kg/m3) |
Insoluble. | |
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Vapour Pressure (mm.Hg./20 °C) |
185 (based on major component) | |
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Density (kg/m3) |
0.7 - 0.9. (measured as kg/litre) | |
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Auto-flammability (ºC) |
Above 200. | |
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Viscosity (cSt) |
Mobile liquid at ambient temperatures. | |
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Vapour Density (Air = 1) |
Heavier than air. | |
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Evaporation Rate |
7.7 (referenced as n-butyl acetate = 1) (based on major component) | |
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10. STABILITY AND REACTIVITY | ||
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Stability |
Stable under normal conditions. | |
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Conditions to Avoid |
Temperatures in excess of 50 °C. Exposure to direct sunlight. | |
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Materials to Avoid |
Strong oxidising agents. | |
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Hazardous Decomposition Products |
Combustion will generate: smoke, possibly thick and choking, resulting in zero visibility. | |
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11. TOXICOLOGICAL INFORMATION | ||
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Acute Toxicity |
Low order of acute toxicity. | |
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12. ECOLOGICAL INFORMATION | ||
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Mobility |
The product is volatile/gaseous and will partition to the air phase. If released to water the product will float. | |
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Persistence/Degradability |
The product is expected to be resistant to biodegradation. | |
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Bio-accumulation |
Product is not expected to bioaccumulate. | |
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13. DISPOSAL | ||
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Product Disposal |
Dispose of in accordance with all applicable local and national regulations. | |
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Container Disposal |
Plastic caps and empty aerosols may be recycled via appropriate routes. Empty aerosols may be disposed of by authorised landfill. Do not incinerate closed containers. | |
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14. TRANSPORT INFORMATION | ||
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UN Number |
1950 | |
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UN Proper Shipping Name |
Aerosols | |
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UN Class |
2.1 | |
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UK Proper Shipping Name |
Aerosols | |
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UK Classification |
2.1 | |
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UK Transport Category |
2 | |
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ADR/RID - Description |
Aerosols. | |
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ADR/RID - Class |
2 | |
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ADR/RID - Item No. |
5°F | |
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IMDG - Proper Shipping Name |
Aerosols | |
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IMDG - Class |
2.1 | |
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IMDG - Page No. |
2102 | |
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IMDG - Ems Number |
2-13 | |
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IMDG - MFAG Table Number |
620 | |
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IATA - Proper Shipping Name |
Aerosols | |
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IATA - Class |
2.1 | |
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Tremcard No. TEC(R) |
20G26 | |
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15. REGULATORY INFORMATION | ||||||||
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Labelling Information |
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Irritant |
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Extremely flammable |
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R phrases |
R12 Extremely flammable. R36 Irritating to eyes. | |||||||
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S phrases |
S16 Keep away from sources of ignition - No Smoking. S51 Use only in well ventilated areas. S23 Do not breathe spray. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. | |||||||
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16. OTHER INFORMATION | ||
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Product Use |
For industrial use only. Marking out of engineering components. | |
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MSDS first issued |
19 August 1997 | |
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MSDS data revised |
25 October 2000 | |
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17. NATIONAL LEGISLATION | ||
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EC Legislation |
EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 88/379/EEC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. | |
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UK Guidance Publications |
EH40, Occupational Exposure Limits, HSE. Revised Annually. | |
